Abou Chaaya, Adib; Le Poitevin, Mathilde; Cabello-Aguilar, Simon; Balme, Sebastien; Bechelany, Mikhael; Kraszewski, Sebastian; Picaud, Fabien; cambedouzou, Julien; Balanzat, Emmanuel; Janot, Jean-Marc; Thami, Thierry; Miele, Philippe; Dejardin, Philippe
Enhanced Ionic Transport Mechanism by Gramicidin A Confined Inside Nanopores Tuned by Atomic Layer Deposition
JOURNAL OF PHYSICAL CHEMISTRY C, 117:15306-15315, JUL 25 2013

The confinement and the understanding of ion transport through ionic channels when they are confined inside solid-state nanopores smaller than 10 nm remains a challenge. Here we report on the fabrication of biomimetic nanopores with high length (5 mu m)/diameter (smaller than 10 nm) ratio obtained using both a track-etched technique and atomic layer deposition on flexible membranes. These membranes present uniform hydrophobic nanopores with a low roughness inside the pores. Gramicidin A is then confined inside nanopores (diameter 10.6, 5.7, and similar to 2 nm) leading to the NaCl ionic transport mechanism through a hybrid nanopore similar to the biological ones especially for small diameter (5.7 and similar to 2 nm).

DOI:10.1021/jp403330d

Find full text with Google Scholar.